Quantitative EPR studies of transition metal ions in oxide, aluminosilicate and polymer matrices
Identifieur interne : 001056 ( Main/Exploration ); précédent : 001055; suivant : 001057Quantitative EPR studies of transition metal ions in oxide, aluminosilicate and polymer matrices
Auteurs : K. Dyrek [Pologne] ; A. Rokosz [Pologne] ; A. Madej [Pologne] ; E. Bidzi Ska [Pologne]Source :
- Applied Magnetic Resonance [ 0937-9347 ] ; 1996-01-01.
Abstract
Abstract: The importance of the proper choice of diamagnetic diluent used for preparation of standards for quantitative EPR measurements is shown by the example of CuSO4 and VOSO4 standards. The results of determination of the stability of chemical composition of VOSO4-K2SO4 standards stored for various periods of time, performed by different analytical methods, are compared. The examples are given to illustrate application of quantitative EPR measurements in the studies of structure and properties of transition metal ions dispersed in various matrices. Changes in the coordination sphere of surface transition metal ions occurring upon adsorption of gas molecules, the degree of dispersion of these ions and the extent of Mn+−Mn+ interactions derived from quantitative EPR measurements are described. The results of investigation of the mechanism of adsorption and catalytic reactions occurring on dispersed transition metal ions are presented.
Url:
DOI: 10.1007/BF03163116
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 001470
- to stream Istex, to step Curation: 000F54
- to stream Istex, to step Checkpoint: 000897
- to stream Main, to step Merge: 001095
- to stream Main, to step Curation: 001056
Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Quantitative EPR studies of transition metal ions in oxide, aluminosilicate and polymer matrices</title>
<author><name sortKey="Dyrek, K" sort="Dyrek, K" uniqKey="Dyrek K" first="K." last="Dyrek">K. Dyrek</name>
</author>
<author><name sortKey="Rokosz, A" sort="Rokosz, A" uniqKey="Rokosz A" first="A." last="Rokosz">A. Rokosz</name>
</author>
<author><name sortKey="Madej, A" sort="Madej, A" uniqKey="Madej A" first="A." last="Madej">A. Madej</name>
</author>
<author><name sortKey="Bidzi Ska, E" sort="Bidzi Ska, E" uniqKey="Bidzi Ska E" first="E." last="Bidzi Ska">E. Bidzi Ska</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:CC8CCCFF0D64D49F1D51709DD75BD0B05C6D7DB4</idno>
<date when="1996" year="1996">1996</date>
<idno type="doi">10.1007/BF03163116</idno>
<idno type="url">https://api.istex.fr/document/CC8CCCFF0D64D49F1D51709DD75BD0B05C6D7DB4/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">001470</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001470</idno>
<idno type="wicri:Area/Istex/Curation">000F54</idno>
<idno type="wicri:Area/Istex/Checkpoint">000897</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000897</idno>
<idno type="wicri:doubleKey">0937-9347:1996:Dyrek K:quantitative:epr:studies</idno>
<idno type="wicri:Area/Main/Merge">001095</idno>
<idno type="wicri:Area/Main/Curation">001056</idno>
<idno type="wicri:Area/Main/Exploration">001056</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Quantitative EPR studies of transition metal ions in oxide, aluminosilicate and polymer matrices</title>
<author><name sortKey="Dyrek, K" sort="Dyrek, K" uniqKey="Dyrek K" first="K." last="Dyrek">K. Dyrek</name>
<affiliation wicri:level="1"><country xml:lang="fr">Pologne</country>
<wicri:regionArea>Department of Inorganic Chemistry, Jagiellonian University, Ingardena 3, 30-060, Cracow</wicri:regionArea>
<wicri:noRegion>Cracow</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Rokosz, A" sort="Rokosz, A" uniqKey="Rokosz A" first="A." last="Rokosz">A. Rokosz</name>
<affiliation wicri:level="1"><country xml:lang="fr">Pologne</country>
<wicri:regionArea>Department of Analytical Chemistry, Jagiellonian University, Cracow</wicri:regionArea>
<wicri:noRegion>Cracow</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Madej, A" sort="Madej, A" uniqKey="Madej A" first="A." last="Madej">A. Madej</name>
<affiliation wicri:level="1"><country xml:lang="fr">Pologne</country>
<wicri:regionArea>Department of Analytical Chemistry, Jagiellonian University, Cracow</wicri:regionArea>
<wicri:noRegion>Cracow</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Bidzi Ska, E" sort="Bidzi Ska, E" uniqKey="Bidzi Ska E" first="E." last="Bidzi Ska">E. Bidzi Ska</name>
<affiliation wicri:level="1"><country xml:lang="fr">Pologne</country>
<wicri:regionArea>Regional Laboratory of Physicochemical Analyses and Structural Research, Cracow</wicri:regionArea>
<wicri:noRegion>Cracow</wicri:noRegion>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j">Applied Magnetic Resonance</title>
<title level="j" type="abbrev">Appl. Magn. Reson.</title>
<idno type="ISSN">0937-9347</idno>
<idno type="eISSN">1613-7507</idno>
<imprint><publisher>Springer-Verlag</publisher>
<pubPlace>Vienna</pubPlace>
<date type="published" when="1996-01-01">1996-01-01</date>
<biblScope unit="volume">10</biblScope>
<biblScope unit="issue">1-3</biblScope>
<biblScope unit="page" from="319">319</biblScope>
<biblScope unit="page" to="338">338</biblScope>
</imprint>
<idno type="ISSN">0937-9347</idno>
</series>
<idno type="istex">CC8CCCFF0D64D49F1D51709DD75BD0B05C6D7DB4</idno>
<idno type="DOI">10.1007/BF03163116</idno>
<idno type="ArticleID">BF03163116</idno>
<idno type="ArticleID">Art22</idno>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">0937-9347</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass></textClass>
<langUsage><language ident="en">en</language>
</langUsage>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Abstract: The importance of the proper choice of diamagnetic diluent used for preparation of standards for quantitative EPR measurements is shown by the example of CuSO4 and VOSO4 standards. The results of determination of the stability of chemical composition of VOSO4-K2SO4 standards stored for various periods of time, performed by different analytical methods, are compared. The examples are given to illustrate application of quantitative EPR measurements in the studies of structure and properties of transition metal ions dispersed in various matrices. Changes in the coordination sphere of surface transition metal ions occurring upon adsorption of gas molecules, the degree of dispersion of these ions and the extent of Mn+−Mn+ interactions derived from quantitative EPR measurements are described. The results of investigation of the mechanism of adsorption and catalytic reactions occurring on dispersed transition metal ions are presented.</div>
</front>
</TEI>
<affiliations><list><country><li>Pologne</li>
</country>
</list>
<tree><country name="Pologne"><noRegion><name sortKey="Dyrek, K" sort="Dyrek, K" uniqKey="Dyrek K" first="K." last="Dyrek">K. Dyrek</name>
</noRegion>
<name sortKey="Bidzi Ska, E" sort="Bidzi Ska, E" uniqKey="Bidzi Ska E" first="E." last="Bidzi Ska">E. Bidzi Ska</name>
<name sortKey="Madej, A" sort="Madej, A" uniqKey="Madej A" first="A." last="Madej">A. Madej</name>
<name sortKey="Rokosz, A" sort="Rokosz, A" uniqKey="Rokosz A" first="A." last="Rokosz">A. Rokosz</name>
</country>
</tree>
</affiliations>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001056 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001056 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Wicri/Terre |area= CobaltMaghrebV1 |flux= Main |étape= Exploration |type= RBID |clé= ISTEX:CC8CCCFF0D64D49F1D51709DD75BD0B05C6D7DB4 |texte= Quantitative EPR studies of transition metal ions in oxide, aluminosilicate and polymer matrices }}
This area was generated with Dilib version V0.6.32. |